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- W2025078596 abstract "Addition of M2SCN(CH2R)2 to D(C6H4S)2SbCl in methylene chloride solution leaded to the formation of the stable compounds D(C6H4S)2SbS2CN(CH2R)2 (D = O, R = Me, 1; D = S, R = Me, 2; R = Ph, 3). The new dibenzostibocines derivatives containing two different types of dithioligands were characterized by elemental analysis and spectroscopic studies (IR, 1H and 13C NMR). Single crystal X-ray diffraction determinations of complexes 1–3 revealed that the antimony atom acts as an acceptor atom exhibiting an intramolecular transannular interaction with the donor D atom, expanding its coordination from three to five and displaying a skew trapezoidal local geometry." @default.
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- W2025078596 date "2007-08-01" @default.
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- W2025078596 title "Pentacoordination at antimony in dibenzostibocines via D–Sb transannular interactions (D=O, S): A structural study" @default.
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- W2025078596 doi "https://doi.org/10.1016/j.poly.2007.03.038" @default.
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