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- W2025078826 abstract "Condensation of β-hydroxy alcohols with ferrocenyl chloride gave the corresponding amides which were dehydrated to give ferrocenyl oxazolines in good overall yield. Subsequent lithiation with n-BuLi in the presence of TMEDA and addition of PPh2Cl led to the isolation of (S)-(S)-iPr-phosferrox and (S)-(S)-Me-phosferrox ligands 1 and 2. Their corresponding diastereoisomers, (S)-(R)-iPr-phosferrox and (S)-(R)-Me-phosferrox 3 and 4 were obtained via the intermediacy of removable trimethylsilyl blocking groups. The CD spectra of 1 – 4 and their parent ferrocenyl oxazolines 9 and 10 were obtained." @default.
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- W2025078826 date "1996-05-01" @default.
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- W2025078826 title "Synthesis of phosphinoferrocenyloxazolines. New ligands for asymmetric catalysis" @default.
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- W2025078826 doi "https://doi.org/10.1016/0957-4166(96)00159-0" @default.
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