Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025093522> ?p ?o ?g. }
- W2025093522 endingPage "5688" @default.
- W2025093522 startingPage "5681" @default.
- W2025093522 abstract "Abstract A novel intramolecular hydroacylation of 5‐ and 6‐alkynals leading to α‐alkylidenecycloalkanones was accomplished by using cationic a rhodium( I )/BINAP complex. For all cyclizations described, a single ( E )‐olefin isomer was obtained. At elevated temperature, hydroacylation and double bond migration of 5‐ and 6‐alkynals proceeded in a one‐pot reaction to give cycloalkenones. An intramolecular hydroacylation of a 7‐alkynal was unsuccessful. This method represents an attractive new route to highly functionalized α‐alkylidenecycloalkanones and cycloalkenones." @default.
- W2025093522 created "2016-06-24" @default.
- W2025093522 creator A5023820956 @default.
- W2025093522 creator A5026087101 @default.
- W2025093522 creator A5027039975 @default.
- W2025093522 creator A5043775960 @default.
- W2025093522 date "2004-10-29" @default.
- W2025093522 modified "2023-10-18" @default.
- W2025093522 title "Rhodium-Catalyzed Intramolecular Hydroacylation of 5- and 6-Alkynals: Convenient Synthesis of ?-Alkylidenecycloalkanones and Cycloalkenones" @default.
- W2025093522 cites W1966945689 @default.
- W2025093522 cites W1987904443 @default.
- W2025093522 cites W1992472814 @default.
- W2025093522 cites W2004367708 @default.
- W2025093522 cites W2005008870 @default.
- W2025093522 cites W2006261977 @default.
- W2025093522 cites W2018107444 @default.
- W2025093522 cites W2024051394 @default.
- W2025093522 cites W2029907344 @default.
- W2025093522 cites W2031741167 @default.
- W2025093522 cites W2035999603 @default.
- W2025093522 cites W2037759725 @default.
- W2025093522 cites W2038983064 @default.
- W2025093522 cites W2039083798 @default.
- W2025093522 cites W2047477357 @default.
- W2025093522 cites W2051709000 @default.
- W2025093522 cites W2052891828 @default.
- W2025093522 cites W2060198907 @default.
- W2025093522 cites W2071545047 @default.
- W2025093522 cites W2086698210 @default.
- W2025093522 cites W2088132624 @default.
- W2025093522 cites W2091060011 @default.
- W2025093522 cites W2102329825 @default.
- W2025093522 cites W2108225141 @default.
- W2025093522 cites W2127406764 @default.
- W2025093522 cites W2160621190 @default.
- W2025093522 cites W2336620120 @default.
- W2025093522 cites W2343240613 @default.
- W2025093522 cites W2949233128 @default.
- W2025093522 cites W2949240048 @default.
- W2025093522 cites W2949582886 @default.
- W2025093522 cites W2950148667 @default.
- W2025093522 cites W2951066096 @default.
- W2025093522 cites W2952235459 @default.
- W2025093522 cites W2952600718 @default.
- W2025093522 cites W2952968765 @default.
- W2025093522 cites W2953334891 @default.
- W2025093522 cites W4238231831 @default.
- W2025093522 doi "https://doi.org/10.1002/chem.200400679" @default.
- W2025093522 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15470696" @default.
- W2025093522 hasPublicationYear "2004" @default.
- W2025093522 type Work @default.
- W2025093522 sameAs 2025093522 @default.
- W2025093522 citedByCount "71" @default.
- W2025093522 countsByYear W20250935222012 @default.
- W2025093522 countsByYear W20250935222013 @default.
- W2025093522 countsByYear W20250935222014 @default.
- W2025093522 countsByYear W20250935222015 @default.
- W2025093522 countsByYear W20250935222017 @default.
- W2025093522 countsByYear W20250935222018 @default.
- W2025093522 countsByYear W20250935222019 @default.
- W2025093522 countsByYear W20250935222020 @default.
- W2025093522 countsByYear W20250935222022 @default.
- W2025093522 crossrefType "journal-article" @default.
- W2025093522 hasAuthorship W2025093522A5023820956 @default.
- W2025093522 hasAuthorship W2025093522A5026087101 @default.
- W2025093522 hasAuthorship W2025093522A5027039975 @default.
- W2025093522 hasAuthorship W2025093522A5043775960 @default.
- W2025093522 hasConcept C161790260 @default.
- W2025093522 hasConcept C167456171 @default.
- W2025093522 hasConcept C178790620 @default.
- W2025093522 hasConcept C183882617 @default.
- W2025093522 hasConcept C185592680 @default.
- W2025093522 hasConcept C51886252 @default.
- W2025093522 hasConcept C521398313 @default.
- W2025093522 hasConcept C71240020 @default.
- W2025093522 hasConcept C75079739 @default.
- W2025093522 hasConceptScore W2025093522C161790260 @default.
- W2025093522 hasConceptScore W2025093522C167456171 @default.
- W2025093522 hasConceptScore W2025093522C178790620 @default.
- W2025093522 hasConceptScore W2025093522C183882617 @default.
- W2025093522 hasConceptScore W2025093522C185592680 @default.
- W2025093522 hasConceptScore W2025093522C51886252 @default.
- W2025093522 hasConceptScore W2025093522C521398313 @default.
- W2025093522 hasConceptScore W2025093522C71240020 @default.
- W2025093522 hasConceptScore W2025093522C75079739 @default.
- W2025093522 hasIssue "22" @default.
- W2025093522 hasLocation W20250935221 @default.
- W2025093522 hasLocation W20250935222 @default.
- W2025093522 hasOpenAccess W2025093522 @default.
- W2025093522 hasPrimaryLocation W20250935221 @default.
- W2025093522 hasRelatedWork W2011970047 @default.
- W2025093522 hasRelatedWork W2046052309 @default.
- W2025093522 hasRelatedWork W2079066329 @default.
- W2025093522 hasRelatedWork W2341687746 @default.
- W2025093522 hasRelatedWork W2905238241 @default.
- W2025093522 hasRelatedWork W2949643706 @default.
- W2025093522 hasRelatedWork W2949698693 @default.
- W2025093522 hasRelatedWork W2949740521 @default.