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• W2025095627 abstract "Vacuum-ultraviolet (VUV) radiation causes the dissociation of organic σ bonds such as the C−C and the C−H bonds in polyolefins. The radicals formed in this process were investigated by trapping with nitric oxide. PE, PP, and PS were irradiated in ultrahigh vacuum with the MgF2-filtered radiation of a hydrogen plasma. After an irradiation period of 1 h and an immediate radical trapping, PE, PP, and PS incorporate 1.4, 0.4, and 0.2 atom % nitrogen, respectively, measured by XPS. These nitrogen concentrations correspond to 5.4 × 1020, 1.4 × 1020, and 0.8 × 1020 spins/cm3, respectively. By the fitting of the XPS-N1s peaks, detailed information about the nitrogen functional groups and about the original radical types was obtained." @default.
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• W2025095627 date "1998-10-16" @default.
• W2025095627 modified "2023-10-04" @default.
• W2025095627 title "Nitric Oxide Radical Trapping Analysis on Vacuum-Ultraviolet Treated Polymers" @default.
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• W2025095627 doi "https://doi.org/10.1021/ma9802071" @default.
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