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• W2025100988 endingPage "6800" @default.
• W2025100988 startingPage "6795" @default.
• W2025100988 abstract "Abstract Unlike the facile synthesis of β‐monofluoromethyl alcohols by nucleophilic monofluoromethylation of epoxides, the synthesis of β‐difluoromethyl alcohols by nucleophilic difluoromethylation of epoxides still remains a challenge. Herein, studies on tackling this problem with PhSO(NTBS)CF 2 H ( 2 ; TBS= tert ‐butyldimethylsilyl) are reported. The preorganization of 2 and epoxides with BF 3 ⋅ Et 2 O was found to be crucial for the reaction. The reaction shows excellent regioselectivity and has a broad substrate scope. The facile transformation of the ring‐opened products to β‐difluoromethyl, γ‐difluoromethyl, and β‐difluoromethylenyl alcohols demonstrates the synthetic utility of the reaction." @default.
• W2025100988 created "2016-06-24" @default.
• W2025100988 creator A5031890685 @default.
• W2025100988 creator A5047649448 @default.
• W2025100988 creator A5057635320 @default.
• W2025100988 creator A5079660887 @default.
• W2025100988 date "2014-04-23" @default.
• W2025100988 modified "2023-10-18" @default.
• W2025100988 title "Nucleophilic Difluoromethylation of Epoxides with PhSO(NTBS)CF₂H by a Preorganization Strategy" @default.
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• W2025100988 doi "https://doi.org/10.1002/chem.201402506" @default.
• W2025100988 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24756897" @default.
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