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- W2025102024 abstract "In solid oxide cell operation, the stoichiometry of the air electrode is an important factor for its interaction with electrolyte and interconnect and long-term cell performance. In this study, tri-layer samples of yttria stabilized zirconia (YSZ)/(La0.8Sr0.2)xMnO3 (LSM)/AISI 441 stainless steel are made and thermally treated in dry air atmosphere at 800 °C for 500 h. The air electrode composition is varied by changing the x value in (La0.8Sr0.2)xMnO3 from 0.95 to 1.05 (LSM95, LSM100, and LSM105). The LSM composition segregation, YSZ/LSM/AISI 441 interfacial interaction, and the reaction of volatile chromium species with the LSM surface are characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). Surface segregation of Sr and La are detected for all the LSM samples. Cr deposition is found across the LSM surface. For the LSM95 sample, Sr-containing compound leads to a high Cr content at the YSZ/LSM interface. For the LSM105 sample, on the other hand, the enrichment of La at the YSZ/LSM interface hinders the Cr deposition, leading to a very low Cr content. The mechanisms of LSM elemental surface segregation and Cr deposition are discussed." @default.
- W2025102024 created "2016-06-24" @default.
- W2025102024 creator A5061324786 @default.
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- W2025102024 date "2011-10-01" @default.
- W2025102024 modified "2023-09-25" @default.
- W2025102024 title "Surface and interface behaviors of (La0.8Sr0.2)xMnO3 air electrode for solid oxide cells" @default.
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- W2025102024 doi "https://doi.org/10.1016/j.jpowsour.2011.06.052" @default.
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