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- W2025117631 abstract "Abstract Kinetics of the oxidation of methanol and mono-deutero-methanol by Cr(VI) over a wide range of temperature (25–40°) have been studied in perchloric acid medium at constant ionic strength (μ = 1.0 M) adjusted with sodium perchlorate. Each reaction is first order with respect to the substrate and dichromate concentrations but the order with respect to [H + ] is nearly 3 in each case. Both these reactions take place at almost the same rate under identical experimental conditions. The activation parameters of the reactions are not widely different and the values of Δ H ‡ and Δ S ‡ for the oxidation of methanol are 79.5 kJ mole -1 and - 38.1 J deg -1 mole -1 respectively, whereas the corresponding values for the deuterated compound are 83.8 kJ mole -1 and -23.9 J deg -1 mole -1 . The probable mechanism of the reactions is discussed." @default.
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- W2025117631 date "1985-01-01" @default.
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- W2025117631 title "Kinetics of oxidation of methanol and mono-deutero-methanol by chromium(VI) in perchloric acid medium" @default.
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- W2025117631 doi "https://doi.org/10.1016/s0040-4020(01)83487-6" @default.
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