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- W2025126075 abstract "Monoozonolyses of dienes 2 in methanol gave in each case the corresponding unsaturated α-methoxy hydroperoxides 3. Capture of 2-alkyl-substituted cyclohexanone oxides by methanol was highly diastereoselective, thereby providing exclusively the hydroperoxides derived from attack by methanol from the less hindered face of the carbonyl oxide intermediates. Halonium ion-mediated reactions of the hydroperoxides 3 gave the novel methoxy- or hydroxy-migrated products, together with the expected halogen-substituted 1,2-dioxanes and/or 1,2-dioxepanes, the composition of the product mixture being a function of the halogenating agent utilized and the structure of 3." @default.
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- W2025126075 date "2000-01-27" @default.
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- W2025126075 title "Halonium Ion-Mediated Reaction of Unsaturated Hydroperoxy Acetals. Competition between the Formation of Cyclic Peroxides and the Migration of the Methoxy (or Hydroxy) Group" @default.
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- W2025126075 doi "https://doi.org/10.1021/jo991499m" @default.
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