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• W2025128213 abstract "Far infrared spectra of the surface films formed upon anodic oxidation of copper have been obtained in-situ for the first time in aqueous solution environments using a synchrotron source. The spectroelectrochemical behavior of copper was studied in NaOH and in a dilute solution of KSCN in perchlorate. The oxide film at −0.05 V vs. SCE in 0.1 M NaOH solution has been identified as Cu2O. In the passive region at 0.3 V, CuO and Cu(OH)2 appear to be present on the surface. Vibrational bands observed in 0.025 M KSCN+perchlorate solution are attributed to a multilayer film of copper(I) thiocyanate." @default.
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• W2025128213 date "1998-06-01" @default.
• W2025128213 modified "2023-10-18" @default.
• W2025128213 title "In-situ synchrotron far infrared spectroscopy of surface films on a copper electrode in aqueous solutions" @default.
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• W2025128213 doi "https://doi.org/10.1016/s0022-0728(97)00609-8" @default.
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