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- W2025150314 abstract "The aggregation numbers of the surfactant aggregates in surfactant-containing systems can be measured using the steady-state fluorescence quenching (SSFQ) and the time-resolved fluorescence quenching (TRFQ) methods. From a theoretical point of view the SSFQ method involves much more restrictive assumptions than the TRFQ method. As a result, the range of aggregation numbers that can be measured with SSFQ does not extend to values as high as with TRFQ. Nevertheless, SSFQ is much used because the measurements are easy to perform and only require readily available spectrofluorometers. The purpose of this study was to compare as completely as possible the two methods. For this purpose we have performed systematic determinations of the values of the surfactant aggregation number in micellar solutions in pure water and in water + polymer and oil-in-water microemulsions, using SSFQ and TRFQ. A good agreement between the two methods is observed when the quenching rate constant of the fluorescent probe (here pyrene..." @default.
- W2025150314 created "2016-06-24" @default.
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- W2025150314 date "1998-08-25" @default.
- W2025150314 modified "2023-10-02" @default.
- W2025150314 title "Micelle Aggregation Numbers of Surfactants in Aqueous Solutions: A Comparison between the Results from Steady-State and Time-Resolved Fluorescence Quenching" @default.
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- W2025150314 doi "https://doi.org/10.1021/la980565x" @default.
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