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- W2025172310 abstract "Internally consistent and properly scaled δ+-substituent constants for (organometal)—methyl groups are derived from several photophysical data sets. These δ+-values are well correlated by a model which considers that stabilization of an adjacent electron-deficient center is proportional to the polarizability of the carbonmetal bond as measured by bond refractions and expressed in a group polarizability function. The model also accommodates the hyperconjugative effects shown by β-deuterium substitution in solvolysis reactions and points to nonhyperconjugative effects as the basis of the Baker-Nathan order. A “best set” of δ+-values for the —CH2MRn substituents (M = C, Si, Ge, Sn, Pb, Hg; R = Me, Ph or X) is suggested. Seventeen other δ+ values for organometallic substituents are presented." @default.
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- W2025172310 date "1981-02-01" @default.
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- W2025172310 title "δ+-substituent constants for (organometal)methyl groups: a bond polarizability model for hyperconjunction" @default.
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- W2025172310 doi "https://doi.org/10.1016/s0022-328x(00)93461-2" @default.
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