FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025193405> ?p ?o ?g. }

• W2025193405 endingPage "2766" @default.
• W2025193405 startingPage "2758" @default.
• W2025193405 abstract "The reaction of [Cu(CH3CN)4]BF4, 6-(4-methoxyl)phenyl-2,2′-bipyridine (designated as MeO-CNN), and/or tricyclohexylphosphine (PCy3) and diimine ligands derived from 4,4′-bipyridine gave four mono- and binuclear copper(I) complexes, [Cu(MeO-CNN)2]BF4 (1), [Cu2(MeO-CNN)2(PCy3)2(4,4′-bipy)](BF4)2 · 1.5CH2Cl2 (2) (bipy = bipyridine), [Cu2(MeO-CNN)2(PCy3)2(bpete)](BF4)2 · 4CH2Cl2 (3) (bpete = trans-1,2-bis(4-pyridyl)ethene) and [Cu2(MeO-CNN)2(PCy3)2(4,4′-azpy)] (BF4)2 · 1.5CH2Cl2 (4) (azpy = azobispyridine). Crystallographic studies of complexes 1–4 show that each copper(I) center adopts a pseudo-tetrahedral coordination geometry. Complexes 2–4 consists of –Cu(MeO-CNN)(PCy3) units which are linked through 4,4′-bipy, bpete and 4,4′-azpy, respectively. The UV–Vis spectra of these four complexes all exhibit intense high-energy absorptions at λmax < 340 nm and broad visible bands in a range of 430–550 nm, ascribed to intraligand (IL π → π∗) transitions and metal-to-ligand charge-transfer (MLCT) transitions, respectively. The density functional theory calculation was used to interpret the absorption spectrum of 1, which further supports the assignment of MLCT character. The binuclear complexes 2 and 3 both display red solid-state emissions centred at 620 and 660 nm from metal-to-ligand charge-transfer excited state, respectively. Interestingly, the electron paramagnetic resonance (EPR) spectral measurements confirm copper(I) complexes oxidized to corresponding copper(II)–halide product upon excitation at 355 nm in dichloromethane solution." @default.
• W2025193405 created "2016-06-24" @default.
• W2025193405 creator A5011872217 @default.
• W2025193405 creator A5036458797 @default.
• W2025193405 creator A5038667092 @default.
• W2025193405 creator A5064897386 @default.
• W2025193405 creator A5066685111 @default.
• W2025193405 creator A5070554076 @default.
• W2025193405 creator A5084533454 @default.
• W2025193405 creator A5088326086 @default.
• W2025193405 date "2007-05-01" @default.
• W2025193405 modified "2023-09-24" @default.
• W2025193405 title "Synthesis, structural and spectroscopic characterization of mono- and binuclear copper(I) complexes with substituted diimine and phosphine ligands" @default.
• W2025193405 cites W1970809788 @default.
• W2025193405 cites W1981261075 @default.
• W2025193405 cites W1987479350 @default.
• W2025193405 cites W1989862193 @default.
• W2025193405 cites W1999320976 @default.
• W2025193405 cites W2001325027 @default.
• W2025193405 cites W2006480186 @default.
• W2025193405 cites W2007078309 @default.
• W2025193405 cites W2007404555 @default.
• W2025193405 cites W2011218868 @default.
• W2025193405 cites W2013386576 @default.
• W2025193405 cites W2016358437 @default.
• W2025193405 cites W2026812720 @default.
• W2025193405 cites W2028677510 @default.
• W2025193405 cites W2033101801 @default.
• W2025193405 cites W2050251853 @default.
• W2025193405 cites W2052265901 @default.
• W2025193405 cites W2055803599 @default.
• W2025193405 cites W2063358107 @default.
• W2025193405 cites W2067322609 @default.
• W2025193405 cites W2068815153 @default.
• W2025193405 cites W2078877422 @default.
• W2025193405 cites W2080260516 @default.
• W2025193405 cites W2087182711 @default.
• W2025193405 cites W2135586915 @default.
• W2025193405 cites W2144683971 @default.
• W2025193405 cites W2160415689 @default.
• W2025193405 cites W2322769463 @default.
• W2025193405 cites W2397787145 @default.
• W2025193405 cites W2952189334 @default.
• W2025193405 cites W333283041 @default.
• W2025193405 doi "https://doi.org/10.1016/j.ica.2007.02.007" @default.
• W2025193405 hasPublicationYear "2007" @default.
• W2025193405 type Work @default.
• W2025193405 sameAs 2025193405 @default.
• W2025193405 citedByCount "28" @default.
• W2025193405 countsByYear W20251934052012 @default.
• W2025193405 countsByYear W20251934052013 @default.
• W2025193405 countsByYear W20251934052014 @default.
• W2025193405 countsByYear W20251934052015 @default.
• W2025193405 countsByYear W20251934052016 @default.
• W2025193405 countsByYear W20251934052017 @default.
• W2025193405 countsByYear W20251934052022 @default.
• W2025193405 countsByYear W20251934052023 @default.
• W2025193405 crossrefType "journal-article" @default.
• W2025193405 hasAuthorship W2025193405A5011872217 @default.
• W2025193405 hasAuthorship W2025193405A5036458797 @default.
• W2025193405 hasAuthorship W2025193405A5038667092 @default.
• W2025193405 hasAuthorship W2025193405A5064897386 @default.
• W2025193405 hasAuthorship W2025193405A5066685111 @default.
• W2025193405 hasAuthorship W2025193405A5070554076 @default.
• W2025193405 hasAuthorship W2025193405A5084533454 @default.
• W2025193405 hasAuthorship W2025193405A5088326086 @default.
• W2025193405 hasConcept C116569031 @default.
• W2025193405 hasConcept C121332964 @default.
• W2025193405 hasConcept C161790260 @default.
• W2025193405 hasConcept C170493617 @default.
• W2025193405 hasConcept C178790620 @default.
• W2025193405 hasConcept C181500209 @default.
• W2025193405 hasConcept C185544564 @default.
• W2025193405 hasConcept C185592680 @default.
• W2025193405 hasConcept C187961010 @default.
• W2025193405 hasConcept C2776303508 @default.
• W2025193405 hasConcept C46141821 @default.
• W2025193405 hasConcept C544778455 @default.
• W2025193405 hasConcept C55493867 @default.
• W2025193405 hasConcept C75473681 @default.
• W2025193405 hasConcept C8010536 @default.
• W2025193405 hasConceptScore W2025193405C116569031 @default.
• W2025193405 hasConceptScore W2025193405C121332964 @default.
• W2025193405 hasConceptScore W2025193405C161790260 @default.
• W2025193405 hasConceptScore W2025193405C170493617 @default.
• W2025193405 hasConceptScore W2025193405C178790620 @default.
• W2025193405 hasConceptScore W2025193405C181500209 @default.
• W2025193405 hasConceptScore W2025193405C185544564 @default.
• W2025193405 hasConceptScore W2025193405C185592680 @default.
• W2025193405 hasConceptScore W2025193405C187961010 @default.
• W2025193405 hasConceptScore W2025193405C2776303508 @default.
• W2025193405 hasConceptScore W2025193405C46141821 @default.
• W2025193405 hasConceptScore W2025193405C544778455 @default.
• W2025193405 hasConceptScore W2025193405C55493867 @default.
• W2025193405 hasConceptScore W2025193405C75473681 @default.
• W2025193405 hasConceptScore W2025193405C8010536 @default.
• W2025193405 hasIssue "8" @default.
• W2025193405 hasLocation W20251934051 @default.

• next