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- W2025202222 abstract "A glass electrophoresis microchip integrated a flow-type chemiluminescence (CL) detection cell has been developed and evaluated. The chip pattern is a double-T-type electrophoretic sample injection and separation combining with a Y-type chemiluminecent detector. The double-T geometry allows for high-efficiency sample injection and geometric definition of sample plug size. The branch of Y was used as CL reagent channel, and the CL reagent was delivered by a lab-made micropump. Bis[(2,4,6-trichlorophenyl)]oxalate-H(2)O(2) CL system was employed to detect dansyl amino acids. On this microchip, dansyl-phenylalanine and -sarcosine were successfully separated by electrophoresis and detected within 250s. The detection limits (S/N=3) of dansyl-phenylalanine and -sarcosine could reach to 2.8 and 3.2muM, respectively, due to the vigorous dilution of sample with CL reagent and timely removal of the waste solution from reaction area." @default.
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- W2025202222 date "2004-11-01" @default.
- W2025202222 modified "2023-10-16" @default.
- W2025202222 title "Integration of a flow-type chemiluminescence detector on a glass electrophoresis chip" @default.
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- W2025202222 doi "https://doi.org/10.1016/j.talanta.2004.04.024" @default.
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