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- W2025210070 abstract "We have investigated the photochemical and thermal isomerization of Schiff bases derived from o-hydroxybenzaldehydes and aromatic or aliphatic diamines. First-order rate constants of the thermal back reaction of the photoinduced isomerization were measured. From the steric requirements for the molecular rearrangement in the isomerization processes, the structure of the photoisomer was assigned to an o-quinoid amine form, while the thermo-induced colour was related to the yield of a zwitterion." @default.
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- W2025210070 date "1986-05-01" @default.
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- W2025210070 title "Photoisomerization and thermoisomerization II: steric requirements for photochromism and thermochromism of N,N'-bis (salicylidene)diamines" @default.
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- W2025210070 doi "https://doi.org/10.1016/0047-2670(86)87034-4" @default.
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