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- W2025221552 abstract "Magnetic field effect (MFE) on the radical pairs (RPs) generated by the photoexcitation of the phenyl pyrylium ion (PP+) in the presence of the electron donor biphenyl has been investigated. A large effect was observed particularly for the BP/PP+ (I) case; the escape yield at 5 T was more than 20 times the zero-field value at a long time delay. The low-field variation of MFE conforms to the pattern expected for the isotropic HFC (hyperfine coupling) mechanism, and the high-field variation conforms to that expected for the relaxation mechanism. The addition of salt causes saturation at a slightly lower field, presumably because of a change in the rotational correlation time (local motion) of PP• at the micellar surface. Introduction of a methyl group in the acceptor reduces the MFE considerably the reason for which is not immediately clear." @default.
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- W2025221552 date "2002-02-16" @default.
- W2025221552 modified "2023-09-23" @default.
- W2025221552 title "Magnetic Field Control of the Back-Electron-Transfer Process Following Photoinduced Electron Transfer (PIET) in Biphenyl/Phenylpyrylium Salts in SDS Micellar Medium" @default.
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- W2025221552 doi "https://doi.org/10.1021/jp012561y" @default.
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