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- W2025222761 abstract "Oxidation of some aryl methyl sulfides and aryl methyl sulfoxides with hydrogen peroxide, mediated by cetylpyridinium tetrakis(diperoxomolybdo)phosphate (PCMP), was performed in chloroform/ethanol. In addition, the stoichiometric oxidation of sulfoxides to sulfones by PCMP was carried out in chloroform. Second-order rate laws, first order with respect to substrate and to PCMP, were observed in both catalytic and stoichiometric processes. Kinetic data seem to indicate that sulfides are oxidized by a bimolecular process which involves a nucleophilic attack of the substrate on the peroxidic oxygen. On the other hand, the possibility of radical incursion is suggested in the oxidation of sulfoxides." @default.
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- W2025222761 date "1991-09-01" @default.
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- W2025222761 title "Oxygen transfer processes to sulfides and sulfoxides mediated by cetylpyridinium tetrakis(diperoxomolybdo)phosphate" @default.
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- W2025222761 doi "https://doi.org/10.1016/0304-5102(91)80085-h" @default.
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