FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025242651> ?p ?o ?g. }

• W2025242651 endingPage "2807" @default.
• W2025242651 startingPage "2801" @default.
• W2025242651 abstract "The polarities (nucleophilicity and electrophilicity) of free radicals in abstraction reactions were studied by the comparison of the stabilization energies due to delocalization of electrons (SEDE) between a radical and a substrate. The stabilization energies were calculated by the CNDO/2 method for several substrate–radical systems. For the reactions of the methyl radical with chlorinated methanes, the nucleophilicity of the radical was well interpreted by the SEDE from the radical to the substrate. Similarly, the nucleophilicity of the hydrogen atom in chlorine abstraction from chlorinated methanes was indicated by the SEDE from the hydrogen atom to the substrate. In an electrophilic reaction such as hydrogen abstraction by the methyl radical from aliphatic hydrocarbons, the activation energy was found to decrease linearly with an increase in the SEDE from the substrate to the radical. This result is consistent with the electrophilic tendency of the reaction. The SEDE calculated for the reactions of a radical with a series of substrate thus indicates the polarity of the free radical in the abstraction reactions." @default.
• W2025242651 created "2016-06-24" @default.
• W2025242651 creator A5006942700 @default.
• W2025242651 creator A5059666463 @default.
• W2025242651 creator A5062450279 @default.
• W2025242651 creator A5085081461 @default.
• W2025242651 date "1979-10-01" @default.
• W2025242651 modified "2023-09-26" @default.
• W2025242651 title "A Molecular Orbital Study on the Nucleophilicity and the Electrophilicity of Free Radicals in Abstraction Reactions" @default.
• W2025242651 cites W135867663 @default.
• W2025242651 cites W1503378437 @default.
• W2025242651 cites W1970036076 @default.
• W2025242651 cites W1970480354 @default.
• W2025242651 cites W1973899958 @default.
• W2025242651 cites W1990920626 @default.
• W2025242651 cites W2017447381 @default.
• W2025242651 cites W2023016193 @default.
• W2025242651 cites W2033830298 @default.
• W2025242651 cites W2054957063 @default.
• W2025242651 cites W2058217120 @default.
• W2025242651 cites W2068128923 @default.
• W2025242651 cites W2086124825 @default.
• W2025242651 cites W2087138441 @default.
• W2025242651 cites W2092555079 @default.
• W2025242651 cites W2145065557 @default.
• W2025242651 cites W2316152340 @default.
• W2025242651 cites W2527392744 @default.
• W2025242651 cites W2621057185 @default.
• W2025242651 cites W3004627112 @default.
• W2025242651 cites W3004648025 @default.
• W2025242651 cites W3004810935 @default.
• W2025242651 cites W3005036788 @default.
• W2025242651 cites W3005100032 @default.
• W2025242651 cites W4229878677 @default.
• W2025242651 doi "https://doi.org/10.1246/bcsj.52.2801" @default.
• W2025242651 hasPublicationYear "1979" @default.
• W2025242651 type Work @default.
• W2025242651 sameAs 2025242651 @default.
• W2025242651 citedByCount "3" @default.
• W2025242651 crossrefType "journal-article" @default.
• W2025242651 hasAuthorship W2025242651A5006942700 @default.
• W2025242651 hasAuthorship W2025242651A5059666463 @default.
• W2025242651 hasAuthorship W2025242651A5062450279 @default.
• W2025242651 hasAuthorship W2025242651A5085081461 @default.
• W2025242651 hasBestOaLocation W20252426511 @default.
• W2025242651 hasConcept C111368507 @default.
• W2025242651 hasConcept C127313418 @default.
• W2025242651 hasConcept C139066938 @default.
• W2025242651 hasConcept C147597530 @default.
• W2025242651 hasConcept C155647269 @default.
• W2025242651 hasConcept C161790260 @default.
• W2025242651 hasConcept C17365422 @default.
• W2025242651 hasConcept C178790620 @default.
• W2025242651 hasConcept C178907741 @default.
• W2025242651 hasConcept C185592680 @default.
• W2025242651 hasConcept C2776640939 @default.
• W2025242651 hasConcept C2777289219 @default.
• W2025242651 hasConcept C2780263894 @default.
• W2025242651 hasConcept C29773484 @default.
• W2025242651 hasConcept C32909587 @default.
• W2025242651 hasConcept C50027330 @default.
• W2025242651 hasConcept C70050531 @default.
• W2025242651 hasConcept C75473681 @default.
• W2025242651 hasConcept C81022585 @default.
• W2025242651 hasConcept C95306019 @default.
• W2025242651 hasConceptScore W2025242651C111368507 @default.
• W2025242651 hasConceptScore W2025242651C127313418 @default.
• W2025242651 hasConceptScore W2025242651C139066938 @default.
• W2025242651 hasConceptScore W2025242651C147597530 @default.
• W2025242651 hasConceptScore W2025242651C155647269 @default.
• W2025242651 hasConceptScore W2025242651C161790260 @default.
• W2025242651 hasConceptScore W2025242651C17365422 @default.
• W2025242651 hasConceptScore W2025242651C178790620 @default.
• W2025242651 hasConceptScore W2025242651C178907741 @default.
• W2025242651 hasConceptScore W2025242651C185592680 @default.
• W2025242651 hasConceptScore W2025242651C2776640939 @default.
• W2025242651 hasConceptScore W2025242651C2777289219 @default.
• W2025242651 hasConceptScore W2025242651C2780263894 @default.
• W2025242651 hasConceptScore W2025242651C29773484 @default.
• W2025242651 hasConceptScore W2025242651C32909587 @default.
• W2025242651 hasConceptScore W2025242651C50027330 @default.
• W2025242651 hasConceptScore W2025242651C70050531 @default.
• W2025242651 hasConceptScore W2025242651C75473681 @default.
• W2025242651 hasConceptScore W2025242651C81022585 @default.
• W2025242651 hasConceptScore W2025242651C95306019 @default.
• W2025242651 hasIssue "10" @default.
• W2025242651 hasLocation W20252426511 @default.
• W2025242651 hasOpenAccess W2025242651 @default.
• W2025242651 hasPrimaryLocation W20252426511 @default.
• W2025242651 hasRelatedWork W2031268520 @default.
• W2025242651 hasRelatedWork W2035524773 @default.
• W2025242651 hasRelatedWork W2044558977 @default.
• W2025242651 hasRelatedWork W2083986083 @default.
• W2025242651 hasRelatedWork W2106546487 @default.
• W2025242651 hasRelatedWork W2196866880 @default.
• W2025242651 hasRelatedWork W2949147666 @default.
• W2025242651 hasRelatedWork W2949686027 @default.
• W2025242651 hasRelatedWork W3165034457 @default.

• next