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• W2025274382 endingPage "3074" @default.
• W2025274382 startingPage "3045" @default.
• W2025274382 abstract "The structures of 283 compounds of general formula [MLm](μ-A)[M′L′n] (M, M′ = d-or ƒ-block element, L, L′ = ligands0(s), A = p-block element) with respect to the MAM angle (θ). Molecular orbital (primarily extended Hückel) and statistical methods were used for the analysis. It is shown that compounds with 170 < θ < 180° are “linear”. For all [MLn]2(μ-A) compounds except [η-C5R5)2MLn2(η-A), the, MAM interaction consists of cylindrical symmetrical sets of π and δ-orbitals derived from the d-orbitals of the M atoms and the p-orbitals on the A atom. Free rotation of the two MLn units with respect to one another can occur to minimize steric repulsion across the MAM bridge. For [ML5]2(μ-A) compounds with 0–8 electrons on the two metal atoms, the θ angle is determined by intramolecular steric repulsion of the ML5" @default.
• W2025274382 created "2016-06-24" @default.
• W2025274382 creator A5022115285 @default.
• W2025274382 creator A5047087274 @default.
• W2025274382 date "1996-06-01" @default.
• W2025274382 modified "2023-10-14" @default.
• W2025274382 title "An investigation of the MAM angle in compounds of general formula [MLn]2(μ-A)" @default.
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