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- W2025284615 abstract "This work describes the use of ethyl (5S)-carboethoxy-2-pyrrolidinone (ethyl pyroglutamate) as a chiral starting material for use in radical cyclizations reactions. Pyroglutamate is converted to a 5-iodomethyl-N-allylic-2-pyrrolidinone that undergoes radical cyclization under mild conditions. The products are 6-substituted pyrrolizidinone derivatives, produced with high diastereoselectivity." @default.
- W2025284615 created "2016-06-24" @default.
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- W2025284615 date "1992-04-01" @default.
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- W2025284615 title "Asymmetric radical cyclizations: the synthesis of 6-Alkyl Pyrrolizidin-2-ones" @default.
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- W2025284615 doi "https://doi.org/10.1016/s0040-4020(01)92242-2" @default.
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