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- W2025292074 abstract "The local structures around Hg and Rb atoms in liquid Hg-Rb alloys have been studied by extended X-ray absorption fine structure (EXAFS) measurements. The EXAFS spectra were obtained for Rb K-, Hg L 1 - and Hg L 111 -edges as a function of composition. The average distances for Rb-Hg and Hg-Hg obtained by simple model fitting are comparable to the values found in the solid Hg 19 Rb 5 crystalline compound, which form Hg n (n = 4 or 5) units around a Rb atom. Based on these results, the anomalous behavior on the electronic properties of liquid Hg-alkali alloys, such as the maximum of the electrical resistivity at 60 at.% alkali, is discussed." @default.
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- W2025292074 date "2002-10-01" @default.
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- W2025292074 title "Local structure in liquid Hg–Rb alloys studied by EXAFS" @default.
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- W2025292074 doi "https://doi.org/10.1016/s0022-3093(02)01652-6" @default.
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