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- W2025339904 abstract "The Hofmeister or lyotropic series arrange ions according to their ability to salt out polymers [1] and also according to their effects on various bulk, surface and interfacial properties of water, aqueous solutions and colloidal dispersions [2]. The quantitative assignment of lyotropic numbers to individual ions is based on a cumbersome procedure involving flocculation of agar or gelatin sols [3,4]. Nonionic surfactants owe their solubility to hydration of the polyoxyethylene moiety, which decreas with increasing temperature. On heating, they precipitate reversibly at the cloud point (CP). The CP is raised and lowered by salting-in and salting-out electrolytes, respectively (5–7). The CP shift values of anions were found to be related by a smooth curve to their lyotropic numbers. In view of the rapidity and accuracy of measuring CP's and determining the effect of anions thereon, anionic CP shift values can be used to obtain lyotropic numbers." @default.
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- W2025339904 date "1984-10-01" @default.
- W2025339904 modified "2023-09-23" @default.
- W2025339904 title "Lyotropic numbers of anions from cloud point changes of nonionic surfactants" @default.
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- W2025339904 doi "https://doi.org/10.1016/0166-6622(84)80234-6" @default.
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