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- W2025361570 abstract "The decomposition of 1-phenylethyl hydroperoxide (HROOH) catalyzed by methylcobaloxime (Co(III)) at 70 °C has been investigated in oxygen-free chlorobenzene-acetonitrile solvent. The rate of hydroperoxide decomposition increases with increasing conversion until it reaches a maximum, followed by a decrease. The maximum rate coincides with the maximum of the absorbance of the reaction mixture. A simple mechanism has been suggested which describes the kinetics of the overall reaction and explains (i) the linear dependence of the maximal decomposition rate of the hydroperoxide on the initial substrate concentration, (ii) the relation between d[Co(III)]/dt and [HROOH]0, as well as between (d[HROOH]/dt)max and [Co(III)]0, observed experimentally. Deactivation of the catalytically active species takes place with participation of the hydroperoxide." @default.
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- W2025361570 date "1988-04-01" @default.
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- W2025361570 title "Decomposition of 1-phenylethyl hydroperoxide by methyl(pyridine)-bis(dimethylglyoximato)-cobalt(III)" @default.
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- W2025361570 doi "https://doi.org/10.1016/0304-5102(88)85026-0" @default.
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