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- W2025363456 abstract "An approximate analytic expression is derived, based on a novel model for the reactive–diffusive processes in a electrochemiluminescence (ecl) experiment. The physical system treated is one in which ecl is produced by stepping the voltage of a planar electrode to the diffusion-limited reduction value for an emitter species in the presence of a bulk oxidant precursor (9,10-DPA with benzoyl peroxide). The unknown rate constants are determined by a least-squares curve-fitting computer code. The model, though crude, provides an excellent fit to the ecl intensity versus time data, including the rise portion of the curve." @default.
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- W2025363456 date "1981-01-01" @default.
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- W2025363456 title "Model for diffusion-limited electrochemiluminescence" @default.
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- W2025363456 doi "https://doi.org/10.1002/jcc.540020403" @default.
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