Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025367078> ?p ?o ?g. }
- W2025367078 endingPage "13670" @default.
- W2025367078 startingPage "13659" @default.
- W2025367078 abstract "The new borates Fe(II)(6)B(22)O(39)·H(2)O (colourless) and Co(II)(6)B(22)O(39)·H(2)O (dichroic: red/bluish) were synthesised under the high-pressure/high-temperature conditions of 6 GPa and 880 °C (Fe)/950 °C (Co) in a Walker-type multi-anvil apparatus. The compounds crystallise in the orthorhombic space group Pmn2(1) (Z=2) with the lattice parameters a=771.9(2), b=823.4(2), c=1768.0(4) pm, V=1.1237(4) nm(3), R(1)=0.0476, wR(2)=0.0902 (all data) for Fe(6)B(22)O(39)·H(2)O and a=770.1(2), b=817.6(2), c=1746.9(4) pm, V=1.0999(4) nm(3), R(1)=0.0513, wR(2)=0.0939 (all data) for Co(6)B(22)O(39)·H(2)O. The new structure type of M(6)B(22)O(39)·H(2)O (M=Fe, Co) is built up from corner-sharing BO(4) tetrahedra and BO(3) groups, the latter being distorted and close to BO(4) tetrahedra if additional oxygen atoms of the neighbouring BO(4) tetrahedra are considered in the coordination sphere. This situation can be regarded as an intermediate state in the formation of edge-sharing tetrahedra. The structure consists of corrugated multiple layers interconnected by BO(3)/BO(4) groups to form Z-shaped channels. Inside these channels, iron and cobalt show octahedral (M1, M3, M4, M5) and strongly distorted tetrahedral (M2, M6) coordination by oxygen atoms. Co(II)(6)B(22)O(39)·H(2)O is dichroic and the low symmetry of the chromophore [Co(II)O(4)] is reflected by the polarised absorption spectra (Δ(t)=4650 cm(-1), B=878 cm(-1))." @default.
- W2025367078 created "2016-06-24" @default.
- W2025367078 creator A5003289382 @default.
- W2025367078 creator A5042797967 @default.
- W2025367078 creator A5045264214 @default.
- W2025367078 creator A5048728071 @default.
- W2025367078 creator A5056205919 @default.
- W2025367078 creator A5064563706 @default.
- W2025367078 creator A5081964214 @default.
- W2025367078 date "2010-10-13" @default.
- W2025367078 modified "2023-10-18" @default.
- W2025367078 title "Intermediate States on the Way to Edge-Sharing BO4 Tetrahedra in M6B22O39⋅H2O (M=Fe, Co)" @default.
- W2025367078 cites W1539796472 @default.
- W2025367078 cites W1650647335 @default.
- W2025367078 cites W1968475816 @default.
- W2025367078 cites W1969638099 @default.
- W2025367078 cites W1970460486 @default.
- W2025367078 cites W1973566957 @default.
- W2025367078 cites W1974422257 @default.
- W2025367078 cites W1980236772 @default.
- W2025367078 cites W1981114318 @default.
- W2025367078 cites W1988156006 @default.
- W2025367078 cites W1996789074 @default.
- W2025367078 cites W1996922733 @default.
- W2025367078 cites W1997043806 @default.
- W2025367078 cites W1997525885 @default.
- W2025367078 cites W2001333270 @default.
- W2025367078 cites W2002947445 @default.
- W2025367078 cites W2028947101 @default.
- W2025367078 cites W2030717056 @default.
- W2025367078 cites W2031314525 @default.
- W2025367078 cites W2033857906 @default.
- W2025367078 cites W2037176523 @default.
- W2025367078 cites W2038378202 @default.
- W2025367078 cites W2038919037 @default.
- W2025367078 cites W2041893040 @default.
- W2025367078 cites W2042621219 @default.
- W2025367078 cites W2042877835 @default.
- W2025367078 cites W2048182432 @default.
- W2025367078 cites W2049221516 @default.
- W2025367078 cites W2051877347 @default.
- W2025367078 cites W2065476482 @default.
- W2025367078 cites W2066957142 @default.
- W2025367078 cites W2070550429 @default.
- W2025367078 cites W2074019256 @default.
- W2025367078 cites W2075570295 @default.
- W2025367078 cites W2079429281 @default.
- W2025367078 cites W2082449201 @default.
- W2025367078 cites W2082530347 @default.
- W2025367078 cites W2092059092 @default.
- W2025367078 cites W2093633598 @default.
- W2025367078 cites W2095977641 @default.
- W2025367078 cites W2101741054 @default.
- W2025367078 cites W2105520783 @default.
- W2025367078 cites W2106656648 @default.
- W2025367078 cites W2107171598 @default.
- W2025367078 cites W2108123274 @default.
- W2025367078 cites W2131350133 @default.
- W2025367078 cites W2147906174 @default.
- W2025367078 cites W21801684 @default.
- W2025367078 cites W2317358779 @default.
- W2025367078 cites W2325318203 @default.
- W2025367078 cites W2329458619 @default.
- W2025367078 cites W2332286617 @default.
- W2025367078 cites W2900188564 @default.
- W2025367078 cites W2949491489 @default.
- W2025367078 cites W2949621782 @default.
- W2025367078 cites W2950461732 @default.
- W2025367078 cites W2950721782 @default.
- W2025367078 cites W2952812663 @default.
- W2025367078 cites W2953211745 @default.
- W2025367078 cites W3022078164 @default.
- W2025367078 cites W4205726323 @default.
- W2025367078 cites W4233642340 @default.
- W2025367078 cites W4234203492 @default.
- W2025367078 cites W4243035698 @default.
- W2025367078 cites W4243524177 @default.
- W2025367078 cites W77113112 @default.
- W2025367078 doi "https://doi.org/10.1002/chem.201001611" @default.
- W2025367078 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20945444" @default.
- W2025367078 hasPublicationYear "2010" @default.
- W2025367078 type Work @default.
- W2025367078 sameAs 2025367078 @default.
- W2025367078 citedByCount "35" @default.
- W2025367078 countsByYear W20253670782012 @default.
- W2025367078 countsByYear W20253670782013 @default.
- W2025367078 countsByYear W20253670782014 @default.
- W2025367078 countsByYear W20253670782015 @default.
- W2025367078 countsByYear W20253670782016 @default.
- W2025367078 countsByYear W20253670782017 @default.
- W2025367078 countsByYear W20253670782018 @default.
- W2025367078 countsByYear W20253670782019 @default.
- W2025367078 countsByYear W20253670782020 @default.
- W2025367078 countsByYear W20253670782021 @default.
- W2025367078 countsByYear W20253670782023 @default.
- W2025367078 crossrefType "journal-article" @default.
- W2025367078 hasAuthorship W2025367078A5003289382 @default.
- W2025367078 hasAuthorship W2025367078A5042797967 @default.