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- W2025400332 abstract "Abstract Sodium salts of poly(aniline-5-sulfonic acid) (PAS), The PAS(Na) s, were obtained by the reaction of PAS with NaOH in water. The degree of sodium sulfonation of the PAS(Na) s depended on the feed amount of NaOH. The absorption peak of the PAS(Na) s, corresponding to an exciton transition generated by self-doping in the polymer backbone, decreased with the number of sodium sulfonated units. The PAS(Na) s were subjected to electrochemical oxidation, and the two oxidation peaks shifted to a lower potential as the degree of sodium sulfonation increased. The electrochemical reaction was accompanied by electrochromism. Thermoelectric measurements of the PAS(Na) s suggested that the majority of carriers were holes. The Seebeck coefficients ( S ′s) of the PAS(Na) s increased as the degree of sodium sulfonation of the polymers increased." @default.
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- W2025400332 date "2014-10-01" @default.
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- W2025400332 title "Synthesis and optical, electrical, and thermoelectric properties of sodium salts of polyaniline sulfonic acid" @default.
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- W2025400332 doi "https://doi.org/10.1016/j.reactfunctpolym.2014.07.023" @default.
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