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• W2025429462 startingPage "11300" @default.
• W2025429462 abstract "The tight ion pair [EtZn(η(3)-C(6)H(6))][CHB(11)Cl(11)]·C(6)H(6) (1·C(6)H(6)) was obtained through β-hydrogen abstraction and concomitant ethene elimination from Et(2)Zn with the trityl salt [Ph(3)C][CHB(11)Cl(11)]. This ionlike species shows catalytic activity in hydrosilylation and intramolecular hydroamination reactions. The amine adduct {CH(2)CHCH(2)C(Ph(2))CH(2)NH(2)}(3)ZnCB(11)Cl(11) (3), which features a rare transition metal-carborane σ bond, was isolated from a hydroamination experiment." @default.
• W2025429462 created "2016-06-24" @default.
• W2025429462 creator A5025632777 @default.
• W2025429462 creator A5045372922 @default.
• W2025429462 date "2011-10-27" @default.
• W2025429462 modified "2023-10-03" @default.
• W2025429462 title "Cationic Ethylzinc Compound: A Benzene Complex with Catalytic Activity in Hydroamination and Hydrosilylation Reactions" @default.
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• W2025429462 doi "https://doi.org/10.1021/ic201921d" @default.
• W2025429462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22032239" @default.
• W2025429462 hasPublicationYear "2011" @default.
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