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- W2025445156 abstract "Anderson's general theory of collision line broadening has been applied to the calculation of the widths of a large number of pure-rotational transitions in H2O, self-broadened by H2O and foreign gas broadened by O2. In the former case only dipole-dipole forces were considired, in the latter only dipole-quadrupole. The method of calculation followed that previously reported for H2O-N2, and was performed on the IBM 7090. The self-broadened widths, at 300° and 360°K, are presented in tabular form; some regularities and averages are graphed and discussed. There is a marked variation from line to line, both in the absolute value and the ratio of self-broadening to N2-broadening. The intensity-weighted value of the latter ratio is 5·49, in agreement with experiment. Individual widths show fair correlation with the few available experimental values. The H2O-O2 widths depend on the uncertain value of the oxygen quadrupole, and are presented only graphically. The correlation with H2O-N2 is close enough so that the H2O-N2 results may be used for atmospheric problems." @default.
- W2025445156 created "2016-06-24" @default.
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- W2025445156 date "1964-05-01" @default.
- W2025445156 modified "2023-09-26" @default.
- W2025445156 title "Calculation of line widths in H2O-H2O and H2O-O2 collisions" @default.
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- W2025445156 doi "https://doi.org/10.1016/0022-4073(64)90006-8" @default.
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