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- W2025447495 abstract "The major product observed in the 147 nm photolysis of 1,1,1-trichloroethane (CH3CCl3) is 1,1-dichloroethylene (CH2CCl2). Vinyl chloride and acetylene, however, are also formed in significant quantities. The CH2CCl2 is undoubtedly produced by the molecular elimination of HCl. Symmetry considerations suggest that the electronically excited state of CH3CCl3 initially formed yields CH2CCl2 via an intermediate electronically excited state of CH3CCl3 of lower symmetry. The olefin itself may well be electronically excited at the time of its formation. Other parallel primary processes include the elimination of molecular chlorine and carbon—carbon bond fission. The extinction coefficient of CH3CCl3 at 147 nm and 296 K was determined to be ϵ = (1/PL)ln (I0/I) = 475 ± 75 cm−1 atm−1." @default.
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- W2025447495 date "1977-01-01" @default.
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- W2025447495 title "Primary processes in the photochemical decomposition of 1,1,1-trichloroethane at 147 nm" @default.
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- W2025447495 doi "https://doi.org/10.1016/0047-2670(77)80016-6" @default.
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