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- W2025458720 abstract "Methods for selective introduction of fluoroalkyl groups into organic molecules are highly desirable. In the formation of fluoroalkyl cyclopropanes, the best results so far showed 75% ee (P. Le Maux, S. Julliard, G. Simoneaux Synthesis 2006, 1701). The Rh2(PTAD)4 catalyst system developed by Davies was unique in producing the chiral cyclopropane 3 in both high yield and enantioselectivity. Furthermore, a single diastereomer was observed. The nature of the aryl groups on the reacting partners did not have a significant impact on the enantioselectivity, except in the case of electron-rich alkenes (3a: 88% ee)." @default.
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- W2025458720 date "2007-08-23" @default.
- W2025458720 modified "2023-09-23" @default.
- W2025458720 title "Synthesis of Trifluoromethyl-Substituted Cyclopropanes" @default.
- W2025458720 doi "https://doi.org/10.1055/s-2007-968857" @default.
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