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- W2025475600 abstract "Abstract Variable temperature binding studies and isothermal titration microcalorimetry were used to probe the thermodynamics of molecular recognition of cis -1,3,5-cyclohexanetricar☐ylic acid by tripodal hosts. Remote intramolecular hydrogen bonds, used to restrict conformationally one of the hosts, exhibit a strong influence on the thermodynamic functions for the binding process ΔH and ΔS, with little effect on ΔG. This suggests that the conformational lock imposed by the intramolecular hydrogen bonds organizes the receptor in a conformation that is not optimal for the binding of the triacid." @default.
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- W2025475600 date "1999-01-01" @default.
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- W2025475600 title "Influence of remote intramolecular hydrogen bonds on the thermodynamics of molecular recognition of cis-1,3,5-cyclohexanetricar☐ylic acid" @default.
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