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• W2025482979 abstract "Remarkable structural changes take place during the metal to insulator first-order transition in ${text{Pr}}_{0.50}{text{Ca}}_{0.50}{text{CoO}}_{3}$: a contraction of the unit-cell volume, the bending of the Co-O-Co bond angle, and a decrease in (Pr,Ca)-O bond distance. However, the Co-O bond length and the volume of the ${text{CoO}}_{6}$ octahedra remain almost unaltered during the transition. In view of these data and the absence of transition in ${({text{Nd}}_{2/3}{text{La}}_{1/3})}_{0.5}{text{Ca}}_{0.5}{text{CoO}}_{3}$, we review the current spin-state transition picture, emphasizing that an active role is played by the $A$-site Pr cations that could be related with the effect of Pr in 123 superconducting cuprates." @default.
• W2025482979 created "2016-06-24" @default.
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• W2025482979 date "2010-02-18" @default.
• W2025482979 modified "2023-10-01" @default.
• W2025482979 title "Role of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>A</mml:mi></mml:math>-site cations in the metal-insulator transition in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mtext>Pr</mml:mtext></mml:mrow><mml:mrow><mml:mn>0.5</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mtext>Ca</mml:mtext></mml:mrow><mml:mrow><mml:mn>0.5</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mtext>CoO</mml…" @default.
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• W2025482979 doi "https://doi.org/10.1103/physrevb.81.054427" @default.
• W2025482979 hasPublicationYear "2010" @default.
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