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- W2025491390 abstract "CH{sub 3}NO{sub 2} addition to CO hydrogenation over Ru/KY led to the formation of partially dehydrogenated CH{sub x} groups, which became indistinguishable from CH{sub x} groups derived from CO hydrogenation. Random reaction of these groups provided hydrocarbon formation along the same reaction pathway that normally occurs during CO hydrogenation over Ru/KY. The additional CH{sub x} groups from CH{sub 3}NO{sub 2} enhanced the rates of chain initiation and propagation to similar extents, leading to increases in the rates of formation of C{sub 2}{sup +} hydrocarbons. Some of these CH{sub x} groups were further dehydrogenated and formed surface carbon, resulting in the incorporation of some carbon from CH{sub 3}NO{sub 2} into CO{sub 2}, an increase in the rate of catalyst deactivation, and suppression of secondary reactions on the support." @default.
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- W2025491390 date "1991-04-01" @default.
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- W2025491390 title "CH3NO2 addition to CO hydrogenation over a Ru/KY catalyst" @default.
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- W2025491390 doi "https://doi.org/10.1016/0021-9517(91)90291-b" @default.
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