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- W2025497005 abstract "Abstract The bismuth(III) strontium oxide Sr 2 Bi 2 O 5 has been synthesized in the low-temperature form, and studied using both single-crystal X-ray and powder neutron diffractometry. All bismuth atoms are in an unusual threefold coordination with oxygen. The compound crystallizes in the orthorhombic space group Pnma with Z = 4 and X-ray cell parameters a = 14.261(3), b = 6.160(2), c = 7.642(3)A. A superlattice, visible in long exposure precession photographs, exists along c (2 × 3.8A). This is due to the ordering of oxygen and vacancies along the c -axial direction, and to resulting displacements of the Bi atoms along c . The structure consists of an ordered intergrowth, along the a -axial direction, of slabs of inverse NiAs-type, with composition Sr 2 O 4 and strings of Bi O Bi···□···Bi O Bi···, where □ represents an oxygen vacancy." @default.
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- W2025497005 date "1991-07-01" @default.
- W2025497005 modified "2023-09-26" @default.
- W2025497005 title "Sr2Bi2O5: A structure containing only 3-coordinated bismuth" @default.
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- W2025497005 doi "https://doi.org/10.1016/0022-4596(91)90292-p" @default.
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