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- W2025503635 abstract "Previous crossed laser-molecular beam experiments on bromoacetyl chloride investigated the influence of electronic nonadiabaticity on the branching between C–Cl and C–Br fission upon 1[n(O),π*(C=O)] excitation at 248 nm. This note identifies an additional contribution to the data from a minor primary C–C fission channel. Using the distribution of kinetic energies imparted to C–C fission products in bromoacetone following 1[n(O),π*(C=O)] excitation as a characteristic one, we reanalyze the Br+ and Cl+ time-of-flight spectra from bromoacetyl chloride at 248 nm to identify any contribution from C–C bond fission. We find that a small portion of the Br+ signal results from CH2Br fragments from C–C fission. Although this in no way alters the major conclusions from this previous work, it does slightly alter the P(ET) derived for C–Br fission and the C–Cl:C–Br branching ratio from bromoacetyl chloride." @default.
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- W2025503635 date "1994-03-01" @default.
- W2025503635 modified "2023-10-12" @default.
- W2025503635 title "Uncovering a minor C–C fission channel in bromoacetyl chloride" @default.
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- W2025503635 doi "https://doi.org/10.1063/1.467245" @default.
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