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- W2025536183 abstract "The cover picture symbolizes a domino reaction consisting of a carbopalladation, cyclopropyl ring opening, β-hydride elimination and a subsequent [4+2] cycloaddition. This game is set off when a mixture of bicyclopropylidene, an aryl (or an alkenyl) iodide and a dienophile is treated with a palladium catalyst at elevated temperature (80–100 °C). The key factor in this new three-component reaction is that the carbopalladation of the unusually reactive tetrasubstituted alkene bicyclopropylidene proceeds more rapidly than that of the dienophile, which usually also is a typical Heck-coupling substrate. This work is described in more detail by de Meijere et al. on p. 2350 ff. The image was generated by Stefan Beushausen with the program COREL DRAW." @default.
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- W2025536183 date "2002-05-17" @default.
- W2025536183 modified "2023-09-27" @default.
- W2025536183 title "Cover Picture: Chem. Eur. J. 10/2002" @default.
- W2025536183 doi "https://doi.org/10.1002/1521-3765(20020517)8:10<2207::aid-chem2207>3.0.co;2-p" @default.
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