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- W2025550014 abstract "The phase diagram for the pseudo-binary system V2O5-Nb2O5 was constructed from fusion characteristics and x-ray diffraction data. Three compounds were postulated for the system. The compound VNb9O25 and V2Nb23O62 were found to melt incongruently at about 129O °C and 1322 °C respectively. The third compound occurring at about 93 to 94 mole percent Nb2O5 melted incongruently at approximately 1332 °C. Apparently,Nb2O5 accepted up to 5 mole percent V2O5 in solid solution, however, V2O5 did not accept any appreciable Nb2O5 in solid solution. In addition, the Nb2O5 rich portions of the following binary systems were reinvestigated: ZnO - Nb2O5, NiO - Nb2O5, A12O3 - Nb2O5, TiO2 - Nb2O5, and ZrO2 - Nb2O5. In each case an Nb2O5 solid solution had been reported previously in excess of 9O mole percent Nb2O5.However, subsequent data indicated that these Nb2O5 solid solutions contained discrete compounds which are related to those found in the pseudo-binary V2O5 - Nb2O5." @default.
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- W2025550014 date "1965-03-01" @default.
- W2025550014 modified "2023-10-14" @default.
- W2025550014 title "Phase equilibria in the system vanadium oxide-niobium oxide" @default.
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- W2025550014 doi "https://doi.org/10.6028/jres.069a.014" @default.
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