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- W2025552496 startingPage "880" @default.
- W2025552496 abstract "Electron paramagnetic resonance of Mn 2+ in a single crystal of tris-sarcosine calcium bromide (TSCBr), as a function of temperature and orientation, has been studied. These studies suggest the existence of two chemically equivalent but physically non equivalent Mn 2+ site in a unit cell of TSCBr. Of the two space groups determined by neutron diffraction studies, Pnma and Pn2 1 a, EPR studies are in conformity with the space group Pnma. The dielectric constant measurements in TSCBr do not show any anomaly in the temperature interval 300–100 K. Tris-sarcosine calcium chloride (TSCC, space group Pnma in the paraelectric phase) undergoes a ferroelectric phase transition at 127 K. Replacement of Cl by Br is expected to introduce changes in the N-H..X bond (X=Cl, Br) and hence, we believe, protons in the N-H..Cl bond may be playing an important role in the mechanism of ferroelectricity in TSCC." @default.
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- W2025552496 date "1975-10-01" @default.
- W2025552496 modified "2023-09-25" @default.
- W2025552496 title "Electron Paramagnetic Resonance Study of Mn<sup>2+</sup> in Tris-Sarcosine Calcium Bromide" @default.
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- W2025552496 doi "https://doi.org/10.1143/jpsj.39.880" @default.
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