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- W2025565585 abstract "N-Nitroso-N′-methyl-piperazin (I) lagert sich bei der Bestrahlung in alkoholischer Salzsäure in 1-Methyl-3-oximino-piperazin (II) um. Dagegen entsteht aus N-Nitrosomorpholin (IIIa) unter gleichen Bedingungen N-Acetamidomorpholin (IVa). Acethydrazide des Typs IV liegen bei Raumtemperatur als Gemische zweier Rotamerer vor, deren Verhältnis stark lösungsmittelabhängig ist. In (CD3)2SO wurden Koaleszenztemperaturen und freie Aktivierungsthalpien der Rotation um die CONBindung bestimmt." @default.
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- W2025565585 date "1971-01-01" @default.
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- W2025565585 title "Eine photochemisch ausgelöste Reduktion von N-Nitrosomorpholin" @default.
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- W2025565585 doi "https://doi.org/10.1002/hlca.19710540223" @default.
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