Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025571511> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2025571511 endingPage "1890" @default.
- W2025571511 startingPage "1885" @default.
- W2025571511 abstract "Interfacial adsorption of chloro(5,10,15,20-tetraphenylporphyrinato)manganese(III), [Mn(tpp)Cl], at the interface of toluene/aqueous sodium hydrogensulfate was studied by means of an UV/vis external reflection (ER) spectroscopy and interfacial tension measurements. The s-polarized ER spectrum showed higher sensitivity than the p-polarized one at the incident angle of 70.8°. A linear correlation sililar to Beer’s law was obtained between the s-polarized ER absorbance and the interfacial concentration determined from the interfacial tension. The molar ER coefficient at the maximum wavelength of 478 nm was determined as −8.41×105 (mol−1 dm2). The effect of chloride ion concentration on the ER spectra suggested that the interfacial species at toluene/0.1 mol dm−3 sodium hydrogensulfate solution (pH 1.7) was Mn(tpp)(H2O)+i. The interfacial adsorption could be analyzed according to the Langmuir isotherm; the equilibrium constant for the adsorption reaction of Mn(tpp)Clo + H2O →← Mn(tpp)(H2O)+i + Cl− was determined as 59.6. Furthermore, it was suggested that chloride ions were preferentially distributing at the diffuse layer under low chloride ion concentrations." @default.
- W2025571511 created "2016-06-24" @default.
- W2025571511 creator A5011873187 @default.
- W2025571511 creator A5034739026 @default.
- W2025571511 date "2001-10-01" @default.
- W2025571511 modified "2023-10-10" @default.
- W2025571511 title "Axial Hydration and Adsorption of Chloro(5,10,15,20-tetraphenylporphyrinato)manganese(III) at the Toluene/Water Interface, Studied by External Reflection Spectrophotometry" @default.
- W2025571511 cites W1966373741 @default.
- W2025571511 cites W1966522702 @default.
- W2025571511 cites W1968921381 @default.
- W2025571511 cites W1984203579 @default.
- W2025571511 cites W1984550118 @default.
- W2025571511 cites W1994962458 @default.
- W2025571511 cites W1998847707 @default.
- W2025571511 cites W2006213348 @default.
- W2025571511 cites W2017509326 @default.
- W2025571511 cites W2030835372 @default.
- W2025571511 cites W2045308877 @default.
- W2025571511 cites W2054893179 @default.
- W2025571511 cites W2057763027 @default.
- W2025571511 cites W2080833223 @default.
- W2025571511 cites W2083263251 @default.
- W2025571511 cites W2087879462 @default.
- W2025571511 cites W2133246531 @default.
- W2025571511 doi "https://doi.org/10.1246/bcsj.74.1885" @default.
- W2025571511 hasPublicationYear "2001" @default.
- W2025571511 type Work @default.
- W2025571511 sameAs 2025571511 @default.
- W2025571511 citedByCount "15" @default.
- W2025571511 countsByYear W20255715112014 @default.
- W2025571511 crossrefType "journal-article" @default.
- W2025571511 hasAuthorship W2025571511A5011873187 @default.
- W2025571511 hasAuthorship W2025571511A5034739026 @default.
- W2025571511 hasConcept C113196181 @default.
- W2025571511 hasConcept C147789679 @default.
- W2025571511 hasConcept C150394285 @default.
- W2025571511 hasConcept C178790620 @default.
- W2025571511 hasConcept C179104552 @default.
- W2025571511 hasConcept C184651966 @default.
- W2025571511 hasConcept C185592680 @default.
- W2025571511 hasConcept C2778142098 @default.
- W2025571511 hasConcept C2778695967 @default.
- W2025571511 hasConcept C2780343419 @default.
- W2025571511 hasConcept C43617362 @default.
- W2025571511 hasConcept C98015330 @default.
- W2025571511 hasConceptScore W2025571511C113196181 @default.
- W2025571511 hasConceptScore W2025571511C147789679 @default.
- W2025571511 hasConceptScore W2025571511C150394285 @default.
- W2025571511 hasConceptScore W2025571511C178790620 @default.
- W2025571511 hasConceptScore W2025571511C179104552 @default.
- W2025571511 hasConceptScore W2025571511C184651966 @default.
- W2025571511 hasConceptScore W2025571511C185592680 @default.
- W2025571511 hasConceptScore W2025571511C2778142098 @default.
- W2025571511 hasConceptScore W2025571511C2778695967 @default.
- W2025571511 hasConceptScore W2025571511C2780343419 @default.
- W2025571511 hasConceptScore W2025571511C43617362 @default.
- W2025571511 hasConceptScore W2025571511C98015330 @default.
- W2025571511 hasIssue "10" @default.
- W2025571511 hasLocation W20255715111 @default.
- W2025571511 hasOpenAccess W2025571511 @default.
- W2025571511 hasPrimaryLocation W20255715111 @default.
- W2025571511 hasRelatedWork W2020271636 @default.
- W2025571511 hasRelatedWork W2335596810 @default.
- W2025571511 hasRelatedWork W2352940046 @default.
- W2025571511 hasRelatedWork W2363991044 @default.
- W2025571511 hasRelatedWork W2393585337 @default.
- W2025571511 hasRelatedWork W2799954782 @default.
- W2025571511 hasRelatedWork W2964994476 @default.
- W2025571511 hasRelatedWork W3080889939 @default.
- W2025571511 hasRelatedWork W47098518 @default.
- W2025571511 hasRelatedWork W2088718888 @default.
- W2025571511 hasVolume "74" @default.
- W2025571511 isParatext "false" @default.
- W2025571511 isRetracted "false" @default.
- W2025571511 magId "2025571511" @default.
- W2025571511 workType "article" @default.