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- W2025619076 abstract "A comparison is established between ion-rich β alumina and β″ alumina both with compositions ≅ 1.6 Na+ per unit formula and with same compensation mechanism for non stoichiometry (Mg2+). In both materials the ions are distributed between two sites B-R-m.O or Na1Na2 in a ratio 2/3 which does not vary appreciably with T. This leads to the same type of local order but with large and temperature independent coherence lengths for ion rich β alumina and limited ≅ 70A˚and decreasing when T increases for β″ alumina. This results in a large activation energy originating from the bottle-neck aBR site in β alumina compared to the easy activation in the conduction slab in β″ alumina which reveals itself to be the best host lattice for ionic conduction." @default.
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- W2025619076 date "1983-12-01" @default.
- W2025619076 modified "2023-09-26" @default.
- W2025619076 title "Thermal behavior of ion rich βNa and β″Na alumina" @default.
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- W2025619076 doi "https://doi.org/10.1016/0167-2738(83)90253-9" @default.
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