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- W2025622555 abstract "Abstract The glycosylation properties of gulopyranosides have been mapped out, and it is shown that gulose has an intrinsic preference for the formation of 1,2‐c is ‐glycosidic bonds. It is postulated that this glycosylation behaviour originates from nucleophilic attack at the oxacarbenium ion, which adopts the most favourable 3 H 4 conformation. Building on the stereoselectivity of gulose, a guluronic acid alginate trisaccharide was assembled for the first time by using gulopyranosyl building blocks." @default.
- W2025622555 created "2016-06-24" @default.
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- W2025622555 date "2008-10-10" @default.
- W2025622555 modified "2023-10-18" @default.
- W2025622555 title "Stereoselective Synthesis of L-Guluronic Acid Alginates" @default.
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- W2025622555 doi "https://doi.org/10.1002/chem.200800960" @default.
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