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• W2025641282 abstract "In the recent past the space-charge model (Morrison, F. A., and Osterle, J. F., J. Chem. Phys.43, 2111 (1965)) has been extensively used for predicting electrokinetic transport coefficients of charged microcapillary pores. With respect to the other transport coefficients, e.g., the reflection coefficient σ, the solute permeability ω, and the electric transport number ti, this model has played a minor part up to now. In this paper these quantities are evaluated as functions of electrolyte concentrations, pore radius, and density of the pore wall charge. Instead of the method usually followed of solving the Poisson-Boltzmann equation numerically, an approximative analytical approach (Levine, S., Marriott, J. R., Neale, G., and Epstein, N., J. Colloid Interface Sci.52, 136 (1975)) has been chosen. As a result analytical expressions for σ and ω are formulated. For the regime of low electrolyte concentrations explicit equations are presented in which these quantities are expressed in terms of the pore radius and the charge density of the pore wall for a z1–z2 electrolyte. The theoretically predicted behavior of the coefficients is compared with experimental data obtained from osmotic measurements with an aqueous solution of sodium chloride and weakly charged Nuclepore membranes." @default.
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• W2025641282 date "1985-10-01" @default.
• W2025641282 modified "2023-09-26" @default.
• W2025641282 title "The application of the space-charge model to the permeability properties of charged microporous membranes" @default.
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• W2025641282 doi "https://doi.org/10.1016/0021-9797(85)90205-x" @default.
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