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- W2025642703 abstract "The effect of aglycone substitution in the 5′-desoxynucleoside part of cobamide co-enzyme1, modifications in the sugar part of desoxynucleoside ligand, the effect of desoxyglycosyl ligands and modifications in the “lowel” axial position on the stability of CoC and CoNBz bonds in the cyanide cleavage reactions have been studied. Cyanide reactions involving octahedral derivatives of cobamide co-enzymes proceed via two steps: a fast step (k1) corresponding to the substitution of the “lower” 5,6-dimethylbenzimidazole ligand, and a slow step (k2) corresponding to the simultaneous cleavage of the CoC and Nglycoside bonds. Other mechanisms are involved in cyanide reactions with analogues modified at the “lower” axial ligand which presumably possess a similar structure to penta-coordinated complexes." @default.
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- W2025642703 date "1973-11-01" @default.
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- W2025642703 title "The effect of chemical modifications of cobamide co-enzyme on the rate of substitution of trans-axial ligands" @default.
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- W2025642703 doi "https://doi.org/10.1016/s0022-328x(00)86570-5" @default.
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