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• W2025673080 abstract "[reaction: see text] Introduction of an electron-withdrawing group on the aromatic ring of N-methylacetanilide decreased the ratio of the cis conformer, and the ratio correlates well with the Hammett sigma values of the substituents. These steric properties can be applied to achieve amide conformational switching by protonation at the aromatic substituent of 4-[bis(dimethylamino)]-N-methylacetanilide or N-[p-(dimethylamino)phenyl]-N-phenylacetamide." @default.
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• W2025673080 date "2003-03-27" @default.
• W2025673080 modified "2023-10-05" @default.
• W2025673080 title "Amide Conformational Switching Induced by Protonation of Aromatic Substituent" @default.
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• W2025673080 doi "https://doi.org/10.1021/ol034344g" @default.
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