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- W2025676879 abstract "Norbornadiene derivatives are able to store solar energy under isomerisation to a quadricyclane system. This energy can be liberated by a transition-metal catalysed back reaction. With methanol as a solvent during the isomerisation of dimethylquadri-cyclanedicarboxylate I to the dimethylnorbornadienedicarboxylate II the isomeric nortricyclylmethylethers IIIa and IVa are formed as by-products. In the presence of water the formation of the alcohols IIIb and IVb has been observed. As a result of the side-reactions observed, it is concluded that this solar-energy storage system I→II offers no practicability." @default.
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- W2025676879 date "2007-04-24" @default.
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- W2025676879 title "Solar-energy storage with quadricyclane systems" @default.
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- W2025676879 doi "https://doi.org/10.1002/jctb.5030320603" @default.
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