FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025687921> ?p ?o ?g. }

• W2025687921 endingPage "1991" @default.
• W2025687921 startingPage "1978" @default.
• W2025687921 abstract "Abstract The synthesis, characterization, and ring‐opening polymerization of a new cyclic carbonate monomer containing an allyl ester moiety, 5‐methyl‐5‐allyloxycarbonyl‐1,3‐dioxan‐2‐one (MAC), was performed for the first time. MAC was synthesized in five steps in good yield beginning from the starting material, 2,2‐bis(hydroxymethyl)propionic acid. Subsequent polymerization and copolymerizations of the new cyclic carbonate with rac ‐lactide ( rac ‐LA) and ϵ‐caprolactone (CL) were attempted. Rac ‐LA copolymerized well with MAC, but CL copolymerizations produced insoluble products. Oligomeric macroinitiators of MAC and rac ‐LA were synthesized from stannous ethoxide, and both macroinitiators were used for the controlled ring‐opening polymerization of rac ‐LA. The polymerization kinetics were examined by monitoring the disappearance of the characteristic CO ring stretch of the monomer at 1240 cm −1 with real‐time in situ Fourier transform infrared spectroscopy. Postpolymerization oxidation reactions were conducted to epoxidize the unsaturated bonds of the MAC‐functionalized polymers. Epoxide‐containing polymers may allow further organic transformations with various nucleophiles, such as amines, alcohols, and carboxylic acids. NMR was used for microstructure identification of the polymers, and size exclusion chromatography and differential scanning calorimetry were used to characterize the new functionalized poly(ester‐carbonates). © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1978–1991, 2003" @default.
• W2025687921 created "2016-06-24" @default.
• W2025687921 creator A5001082275 @default.
• W2025687921 creator A5015777043 @default.
• W2025687921 creator A5018501071 @default.
• W2025687921 date "2003-05-16" @default.
• W2025687921 modified "2023-10-15" @default.
• W2025687921 title "New aliphatic poly(ester-carbonates) based on 5-methyl-5-allyloxycarbonyl-1,3-dioxan-2-one" @default.
• W2025687921 cites W1523663740 @default.
• W2025687921 cites W1970111938 @default.
• W2025687921 cites W1970263484 @default.
• W2025687921 cites W1974191225 @default.
• W2025687921 cites W1985703189 @default.
• W2025687921 cites W1986393627 @default.
• W2025687921 cites W1993440985 @default.
• W2025687921 cites W1993728577 @default.
• W2025687921 cites W1998789887 @default.
• W2025687921 cites W1999126616 @default.
• W2025687921 cites W2000917283 @default.
• W2025687921 cites W2005974429 @default.
• W2025687921 cites W2009395935 @default.
• W2025687921 cites W2016309934 @default.
• W2025687921 cites W2021351882 @default.
• W2025687921 cites W2025458230 @default.
• W2025687921 cites W2027578803 @default.
• W2025687921 cites W2029864673 @default.
• W2025687921 cites W2033196935 @default.
• W2025687921 cites W2035073102 @default.
• W2025687921 cites W2035192891 @default.
• W2025687921 cites W2052858342 @default.
• W2025687921 cites W2057696506 @default.
• W2025687921 cites W2079592504 @default.
• W2025687921 cites W2082905367 @default.
• W2025687921 cites W2086634837 @default.
• W2025687921 cites W2090332471 @default.
• W2025687921 cites W2091263411 @default.
• W2025687921 cites W2092512936 @default.
• W2025687921 cites W2093225214 @default.
• W2025687921 cites W2094649898 @default.
• W2025687921 cites W2110482898 @default.
• W2025687921 cites W2111079732 @default.
• W2025687921 cites W2114789526 @default.
• W2025687921 cites W2146587881 @default.
• W2025687921 cites W2157318019 @default.
• W2025687921 cites W2168427597 @default.
• W2025687921 doi "https://doi.org/10.1002/pola.10724" @default.
• W2025687921 hasPublicationYear "2003" @default.
• W2025687921 type Work @default.
• W2025687921 sameAs 2025687921 @default.
• W2025687921 citedByCount "52" @default.
• W2025687921 countsByYear W20256879212012 @default.
• W2025687921 countsByYear W20256879212013 @default.
• W2025687921 countsByYear W20256879212014 @default.
• W2025687921 countsByYear W20256879212015 @default.
• W2025687921 countsByYear W20256879212016 @default.
• W2025687921 countsByYear W20256879212017 @default.
• W2025687921 countsByYear W20256879212018 @default.
• W2025687921 countsByYear W20256879212019 @default.
• W2025687921 countsByYear W20256879212020 @default.
• W2025687921 countsByYear W20256879212021 @default.
• W2025687921 countsByYear W20256879212023 @default.
• W2025687921 crossrefType "journal-article" @default.
• W2025687921 hasAuthorship W2025687921A5001082275 @default.
• W2025687921 hasAuthorship W2025687921A5015777043 @default.
• W2025687921 hasAuthorship W2025687921A5018501071 @default.
• W2025687921 hasConcept C121332964 @default.
• W2025687921 hasConcept C161790260 @default.
• W2025687921 hasConcept C166940927 @default.
• W2025687921 hasConcept C178790620 @default.
• W2025687921 hasConcept C178907741 @default.
• W2025687921 hasConcept C185592680 @default.
• W2025687921 hasConcept C188027245 @default.
• W2025687921 hasConcept C203897987 @default.
• W2025687921 hasConcept C2776568683 @default.
• W2025687921 hasConcept C2776920199 @default.
• W2025687921 hasConcept C39519442 @default.
• W2025687921 hasConcept C44228677 @default.
• W2025687921 hasConcept C521977710 @default.
• W2025687921 hasConcept C97355855 @default.
• W2025687921 hasConceptScore W2025687921C121332964 @default.
• W2025687921 hasConceptScore W2025687921C161790260 @default.
• W2025687921 hasConceptScore W2025687921C166940927 @default.
• W2025687921 hasConceptScore W2025687921C178790620 @default.
• W2025687921 hasConceptScore W2025687921C178907741 @default.
• W2025687921 hasConceptScore W2025687921C185592680 @default.
• W2025687921 hasConceptScore W2025687921C188027245 @default.
• W2025687921 hasConceptScore W2025687921C203897987 @default.
• W2025687921 hasConceptScore W2025687921C2776568683 @default.
• W2025687921 hasConceptScore W2025687921C2776920199 @default.
• W2025687921 hasConceptScore W2025687921C39519442 @default.
• W2025687921 hasConceptScore W2025687921C44228677 @default.
• W2025687921 hasConceptScore W2025687921C521977710 @default.
• W2025687921 hasConceptScore W2025687921C97355855 @default.
• W2025687921 hasIssue "13" @default.
• W2025687921 hasLocation W20256879211 @default.
• W2025687921 hasOpenAccess W2025687921 @default.
• W2025687921 hasPrimaryLocation W20256879211 @default.
• W2025687921 hasRelatedWork W1480924375 @default.

• next