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- W2025693208 abstract "This chapter presents a discussion on the bioinorganic chemistry of pterin-containing molybdenum and tungsten enzymes. The chapter focuses on the current results and the interplay of model and enzyme chemistry. Attention is directed to sulfite oxidase and xanthine oxidase, the archetypal examples of molybdenum enzymes, containing, respectively, dioxo-Mo(VI) and oxo-thio-Mo(VI) oxidized centers. Biochemical and model studies of molybdopterin, Mo-co, and related species are described in this chapter. A brief survey on the physical and spectroscopic techniques employed in the study of the enzymes is presented and their impact on the current understanding of the coordination about the molybdenum atom in sulfite oxidase and xanthine oxidase is discussed. Structural and spectroscopic models are also presented in the chapter. The chapter also explains the xanthine oxidase cycle and facets of intramolecular electron transfer in molybdenum enzymes. The pterin-containing tungsten enzymes and the evolving model chemistry are discussed. Current descriptions of the coordination environment of the molybdenum centers of the enzymes rest primarily upon the comparisons of the spectra of the enzymes with the spectra of well-characterized molybdenum complexes. The unexpected discovery that several hyperthermophilic organisms possess pterin-containing tungsten enzymes promises to stimulate the development of oxo-thio-tungsten chemistry." @default.
- W2025693208 created "2016-06-24" @default.
- W2025693208 creator A5018957391 @default.
- W2025693208 creator A5085825695 @default.
- W2025693208 date "1993-01-01" @default.
- W2025693208 modified "2023-10-02" @default.
- W2025693208 title "Bioinorganic Chemistry of Pterin-Containing Molybdenum and Tungsten Enzymes" @default.
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