FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025715044> ?p ?o ?g. }

• W2025715044 endingPage "299" @default.
• W2025715044 startingPage "293" @default.
• W2025715044 abstract "The propyl + O2 reactions are important prototype reactions for general alkyl + O2 systems, possessing the most important reactive channels of larger species while remaining small enough for accurate quantum chemistry calculations and theoretical kinetics. Previous experiments [8] that characterized the production of OH in the propyl + O2 reactions could be only qualitatively modeled by rigorous master-equation calculations, leaving a deficient validation of, for instance, the critical RO2 ↔ QOOH isomerization pathways. This article revisits the combined experimental and modeling study of DeSain et al., using an improved experimental method to obtain time-resolved OH concentrations for pulsed-photolytic Cl-initiated oxidation of propane. The results are modeled with master-equation-based rate coefficients incorporated into a kinetic mechanism. Quantitative agreement can be obtained, providing experimental validation for the OH-producing pathways that are crucial for autoignition. The importance of the rigorous treatment of the kinetics for these highly pressure and temperature dependent reactions is emphasized, as well as the significance of the formally direct pathways such as chemical activation." @default.
• W2025715044 created "2016-06-24" @default.
• W2025715044 creator A5018648223 @default.
• W2025715044 creator A5033355998 @default.
• W2025715044 creator A5048118990 @default.
• W2025715044 creator A5062457472 @default.
• W2025715044 creator A5091388952 @default.
• W2025715044 date "2011-01-01" @default.
• W2025715044 modified "2023-10-08" @default.
• W2025715044 title "New experiments and validated master-equation modeling for OH production in propyl+O2 reactions" @default.
• W2025715044 cites W1611748524 @default.
• W2025715044 cites W19125392 @default.
• W2025715044 cites W1962415203 @default.
• W2025715044 cites W1966334204 @default.
• W2025715044 cites W1974105645 @default.
• W2025715044 cites W1978033043 @default.
• W2025715044 cites W1986107701 @default.
• W2025715044 cites W1988158079 @default.
• W2025715044 cites W1988557394 @default.
• W2025715044 cites W1995849444 @default.
• W2025715044 cites W2015503922 @default.
• W2025715044 cites W2020048991 @default.
• W2025715044 cites W2046033679 @default.
• W2025715044 cites W2056417840 @default.
• W2025715044 cites W2058626067 @default.
• W2025715044 cites W2064201579 @default.
• W2025715044 cites W2064308942 @default.
• W2025715044 cites W2082794077 @default.
• W2025715044 cites W2083250163 @default.
• W2025715044 cites W2090140357 @default.
• W2025715044 cites W2103226679 @default.
• W2025715044 cites W2128151559 @default.
• W2025715044 cites W2156834932 @default.
• W2025715044 cites W2404951105 @default.
• W2025715044 cites W2428696826 @default.
• W2025715044 cites W2691597581 @default.
• W2025715044 cites W4251938939 @default.
• W2025715044 doi "https://doi.org/10.1016/j.proci.2010.06.039" @default.
• W2025715044 hasPublicationYear "2011" @default.
• W2025715044 type Work @default.
• W2025715044 sameAs 2025715044 @default.
• W2025715044 citedByCount "35" @default.
• W2025715044 countsByYear W20257150442012 @default.
• W2025715044 countsByYear W20257150442013 @default.
• W2025715044 countsByYear W20257150442014 @default.
• W2025715044 countsByYear W20257150442015 @default.
• W2025715044 countsByYear W20257150442016 @default.
• W2025715044 countsByYear W20257150442017 @default.
• W2025715044 countsByYear W20257150442018 @default.
• W2025715044 countsByYear W20257150442019 @default.
• W2025715044 countsByYear W20257150442021 @default.
• W2025715044 countsByYear W20257150442022 @default.
• W2025715044 countsByYear W20257150442023 @default.
• W2025715044 crossrefType "journal-article" @default.
• W2025715044 hasAuthorship W2025715044A5018648223 @default.
• W2025715044 hasAuthorship W2025715044A5033355998 @default.
• W2025715044 hasAuthorship W2025715044A5048118990 @default.
• W2025715044 hasAuthorship W2025715044A5062457472 @default.
• W2025715044 hasAuthorship W2025715044A5091388952 @default.
• W2025715044 hasConcept C105923489 @default.
• W2025715044 hasConcept C111163200 @default.
• W2025715044 hasConcept C121332964 @default.
• W2025715044 hasConcept C126661725 @default.
• W2025715044 hasConcept C128805008 @default.
• W2025715044 hasConcept C135889238 @default.
• W2025715044 hasConcept C147597530 @default.
• W2025715044 hasConcept C147789679 @default.
• W2025715044 hasConcept C148898269 @default.
• W2025715044 hasConcept C161790260 @default.
• W2025715044 hasConcept C178790620 @default.
• W2025715044 hasConcept C185592680 @default.
• W2025715044 hasConcept C2780263894 @default.
• W2025715044 hasConcept C36663273 @default.
• W2025715044 hasConcept C62520636 @default.
• W2025715044 hasConcept C64127748 @default.
• W2025715044 hasConcept C65024703 @default.
• W2025715044 hasConcept C8265204 @default.
• W2025715044 hasConcept C84114770 @default.
• W2025715044 hasConcept C97355855 @default.
• W2025715044 hasConceptScore W2025715044C105923489 @default.
• W2025715044 hasConceptScore W2025715044C111163200 @default.
• W2025715044 hasConceptScore W2025715044C121332964 @default.
• W2025715044 hasConceptScore W2025715044C126661725 @default.
• W2025715044 hasConceptScore W2025715044C128805008 @default.
• W2025715044 hasConceptScore W2025715044C135889238 @default.
• W2025715044 hasConceptScore W2025715044C147597530 @default.
• W2025715044 hasConceptScore W2025715044C147789679 @default.
• W2025715044 hasConceptScore W2025715044C148898269 @default.
• W2025715044 hasConceptScore W2025715044C161790260 @default.
• W2025715044 hasConceptScore W2025715044C178790620 @default.
• W2025715044 hasConceptScore W2025715044C185592680 @default.
• W2025715044 hasConceptScore W2025715044C2780263894 @default.
• W2025715044 hasConceptScore W2025715044C36663273 @default.
• W2025715044 hasConceptScore W2025715044C62520636 @default.
• W2025715044 hasConceptScore W2025715044C64127748 @default.
• W2025715044 hasConceptScore W2025715044C65024703 @default.
• W2025715044 hasConceptScore W2025715044C8265204 @default.
• W2025715044 hasConceptScore W2025715044C84114770 @default.

• next