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- W2025736262 abstract "Relativistic g-Hartree equations are derived. Negative energy (Dirac sea) states enter. Their renormalised contributions can be interpreted as Casimir-like energy shifts in the total energy of atoms. The use of optimised g parameters leads to their unambiguous determination. The effect should be particularly important for large Z (Ze2 to 1) and relatively small N, the number of electrons, if transitions between distant configurations, e.g. transitions from the ground state to Rydberg states, are considered. For simplified numerical computations approximate g-Hartree equations are proposed in which Dirac sea contributions are treated in a Thomas-Fermi version." @default.
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- W2025736262 date "1984-12-28" @default.
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- W2025736262 title "Optimised mean-fields for atoms. IV. The Casimir effect and its influence on relativistic mean fields" @default.
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- W2025736262 doi "https://doi.org/10.1088/0022-3700/17/24/016" @default.
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