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• W2025745906 abstract "We describe the employment of steady-state fluorescence spectroscopy coupled to epifluorescence microscopy (fluorescence microspectroscopy) for monitoring the diffusion of the lower-Tg component during heating of a binary blend of poly(n-butyl methacrylate-co-styrene) containing 9-vinylanthracene units attached as fluorescent label (nBMAS) with polystyrene. The segregation of the nBMAS was monitored by simply measuring the emission spectra over areas of a few micrometers at 40 °C (above nBMAS-Tg) near the interfacial region as a function of time, while the morphological changes and the flux of diffusant were readily revealed during the annealing process. The apparent diffusion coefficient, Dap = (1.6 ± 0.1) × 10-6 cm2 s-1, was extracted from the slope of the better linear fitting from the plot of relative intensities (as integrated spectra) vs t1/2." @default.
• W2025745906 created "2016-06-24" @default.
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• W2025745906 date "2004-11-09" @default.
• W2025745906 modified "2023-10-17" @default.
• W2025745906 title "Diffusion of a Single Component in a Binary Polymer Blend upon Annealing Monitored by Fluorescence Microspectroscopy" @default.
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• W2025745906 doi "https://doi.org/10.1021/ma048873r" @default.
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